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3D TRASAR® 3DT120

SAFETY DATA SHEET PRODUCT 3D TRASAR® 3DT120 EMERGENCY TELEPHONE NUMBER(S) (800) 424-9300 (24 Hours) CHEMTREC Nalco Company 1601 W. Diehl Road • Naperville, Illinois 60563-1198 • (630)305-1000

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Text of 3D TRASAR® 3DT120

SAFETY DATA SHEET PRODUCT 3D TRASAR 3DT120 EMERGENCY TELEPHONE NUMBER(S) (800) 424-9300 (24 Hours) CHEMTREC Nalco Company 1601 W. Diehl Road Naperville, Illinois 60563-1198 (630)305-1000 For additional copies of an MSDS visit and request access. 1 / 10 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME : 3D TRASAR 3DT120 APPLICATION : COOLING WATER TREATMENT COMPANY IDENTIFICATION : Nalco Company 1601 W. Diehl Road Naperville, Illinois 60563-1198 EMERGENCY TELEPHONE NUMBER(S) : (800) 424-9300 (24 Hours) CHEMTREC NFPA 704M/HMIS RATING HEALTH : 0 / 1 FLAMMABILITY : 1 / 1 INSTABILITY : 0 / 0 OTHER : 0 0 = Insignificant 1 = Slight 2 = Moderate 3 = High 4 = Extreme * = Chronic Health Hazard 2. COMPOSITION/INFORMATION ON INGREDIENTS Our hazard evaluation has found that this product is not hazardous under 29 CFR 3. HAZARDS IDENTIFICATION **EMERGENCY OVERVIEW** CAUTION May cause irritation with prolonged contact. Do not get in eyes, on skin, on clothing. Do not take internally. Use with adequate ventilation. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. After contact with skin, wash immediately with plenty of water. Wear suitable protective clothing. May evolve oxides of carbon (COx) under fire conditions. PRIMARY ROUTES OF EXPOSURE : Eye, Skin, Inhalation HUMAN HEALTH HAZARDS - ACUTE : EYE CONTACT : May cause irritation with prolonged contact. SKIN CONTACT : May cause irritation with prolonged contact. INGESTION : Not a likely route of exposure. May cause gastrointestinal irritation. SAFETY DATA SHEET PRODUCT 3D TRASAR 3DT120 EMERGENCY TELEPHONE NUMBER(S) (800) 424-9300 (24 Hours) CHEMTREC Nalco Company 1601 W. Diehl Road Naperville, Illinois 60563-1198 (630)305-1000 For additional copies of an MSDS visit and request access. 2 / 10 INHALATION : Not a likely route of exposure. No adverse effects expected. SYMPTOMS OF EXPOSURE : Acute : A review of available data does not identify any symptoms from exposure not previously mentioned. Chronic : A review of available data does not identify any symptoms from exposure not previously mentioned. HUMAN HEALTH HAZARDS - CHRONIC : No adverse effects expected other than those mentioned above. 4. FIRST AID MEASURES EYE CONTACT : Flush affected area with water. If symptoms develop, seek medical advice. SKIN CONTACT : Flush affected area with water. If symptoms develop, seek medical advice. INGESTION : Get medical attention. Do not induce vomiting without medical advice. If conscious, washout mouth and give water to drink. INHALATION : Remove to fresh air, treat symptomatically. If symptoms develop, seek medical advice. NOTE TO PHYSICIAN : Based on the individual reactions of the patient, the physician's judgement should be used to control symptoms and clinical condition. 5. FIRE FIGHTING MEASURES FLASH POINT : Not applicable EXTINGUISHING MEDIA : Water, Carbon dioxide, Dry powder, Foam This product would not be expected to burn unless all the water is boiled away. The remaining organics may be ignitable. Use extinguishing media appropriate for surrounding fire. FIRE AND EXPLOSION HAZARD : May evolve oxides of carbon (COx) under fire conditions. SPECIAL PROTECTIVE EQUIPMENT FOR FIRE FIGHTING : In case of fire, wear a full face positive-pressure self contained breathing apparatus and protective suit. SAFETY DATA SHEET PRODUCT 3D TRASAR 3DT120 EMERGENCY TELEPHONE NUMBER(S) (800) 424-9300 (24 Hours) CHEMTREC Nalco Company 1601 W. Diehl Road Naperville, Illinois 60563-1198 (630)305-1000 For additional copies of an MSDS visit and request access. 3 / 10 6. ACCIDENTAL RELEASE MEASURES PERSONAL PRECAUTIONS : Restrict access to area as appropriate until clean-up operations are complete. Use personal protective equipment recommended in Section 8 (Exposure Controls/Personal Protection). Stop or reduce any leaks if it is safe to do so. Ventilate spill area if possible. METHODS FOR CLEANING UP : SMALL SPILLS: Soak up spill with absorbent material. Place residues in a suitable, covered, properly labeled container. Wash affected area. LARGE SPILLS: Contain liquid using absorbent material, by digging trenches or by diking. Reclaim into recovery or salvage drums or tank truck for proper disposal. Clean contaminated surfaces with water or aqueous cleaning agents. Contact an approved waste hauler for disposal of contaminated recovered material. Dispose of material in compliance with regulations indicated in Section 13 (Disposal Considerations). ENVIRONMENTAL PRECAUTIONS : Do not contaminate surface water., Prevent material from entering sewers or waterways., If drains, streams, soil or sewers become contaminated, notify local authority. 7. HANDLING AND STORAGE HANDLING : Do not get in eyes, on skin, on clothing. Use with adequate ventilation. Do not breathe vapors/gases/dust. Keep the containers closed when not in use. Have emergency equipment (for fires, spills, leaks, etc.) readily available. Ensure all containers are labeled. Use personal protective equipment recommended in Section 8 (Exposure Controls/Personal Protection). STORAGE CONDITIONS : Store in suitable labeled containers. Store the containers tightly closed. UNSUITABLE CONSTRUCTION MATERIAL : Compatibility with Plastic Materials can vary; we therefore recommend that compatibility is tested prior to use. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION OCCUPATIONAL EXPOSURE LIMITS : This product does not contain any substance that has an established exposure limit. ENGINEERING MEASURES : General ventilation is recommended. RESPIRATORY PROTECTION : Where concentrations in air may exceed the limits given in this section, the use of a half face filter mask or air supplied breathing apparatus is recommended. A suitable filter material depends on the amount and type of chemicals being handled. Consider the use of filter type: Multi-contaminant cartridge. with a Particulate pre-filter. In event of emergency or planned entry into unknown concentrations a positive pressure, full-facepiece SCBA should be used. If SAFETY DATA SHEET PRODUCT 3D TRASAR 3DT120 EMERGENCY TELEPHONE NUMBER(S) (800) 424-9300 (24 Hours) CHEMTREC Nalco Company 1601 W. Diehl Road Naperville, Illinois 60563-1198 (630)305-1000 For additional copies of an MSDS visit and request access. 4 / 10 respiratory protection is required, institute a complete respiratory protection program including selection, fit testing, training, maintenance and inspection. HAND PROTECTION : When handling this product, the use of chemical gloves is recommended. The choice of work glove depends on work conditions and what chemicals are handled, but we have positive experience under light handling conditions using gloves made from PVC Gloves should be replaced immediately if signs of degradation are observed. Breakthrough time not determined as preparation, consult PPE manufacturers. SKIN PROTECTION : See general advice. EYE PROTECTION : Wear safety glasses with side-shields. HYGIENE RECOMMENDATIONS : Use good work and personal hygiene practices to avoid exposure. Consider the provision in the work area of a safety shower and eyewash. Always wash thoroughly after handling chemicals. When handling this product never eat, drink or smoke. HUMAN EXPOSURE CHARACTERIZATION : Based on our recommended product application and personal protective equipment, the potential human exposure is: Low 9. PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL STATE Liquid APPEARANCE Clear Yellow ODOR Neutral SPECIFIC GRAVITY - SOLUBILITY IN WATER Complete pH (100 %) - VISCOSITY - cst POUR POINT F / C VOC CONTENT % Calculated Note: These physical properties are typical values for this product and are subject to change. 10. STABILITY AND REACTIVITY STABILITY : Stable under normal conditions. HAZARDOUS POLYMERIZATION : Hazardous polymerization will not occur. SAFETY DATA SHEET PRODUCT 3D TRASAR 3DT120 EMERGENCY TELEPHONE NUMBER(S) (800) 424-9300 (24 Hours) CHEMTREC Nalco Company 1601 W. Diehl Road Naperville, Illinois 60563-1198 (630)305-1000 For additional copies of an MSDS visit and request access. 5 / 10 CONDITIONS TO AVOID : Extremes of temperature MATERIALS TO AVOID : Contact with strong oxidizers ( chlorine, peroxides, chromates, nitric acid, perchlorate, concentrated oxygen, permanganate) may generate heat, fires, explosions and/or toxic vapors. Bases Contact with strong alkalies ( ammonia and its solutions, carbonates, sodium hydroxide (caustic), potassium hydroxide, calcium hydroxide (lime), cyanide, sulfide, hypochlorites, chlorites) may generate heat, splattering or boiling and toxic vapors. SO2 may react with vapors from neutralizing amines and may produce a visible cloud of amine salt particles. HAZARDOUS DECOMPOSITION PRODUCTS : Under fire conditions: Oxides of carbon 11. TOXICOLOGICAL INFORMATION The following results are for the product, unless otherwise indicated. ACUTE ORAL TOXICITY : Species: Rat LD50: 5,000 mg/kg Test Descriptor: Similar Product ACUTE DERMAL TOXICITY : Species: Rabbit LD50: > 2,000 mg/kg Test Descriptor: Similar Product SENSITIZATION : This product is not expected to be a sensitizer. CARCINOGENICITY : None of the substances in this product are listed as carcinogens by the International Agency for Research on Cancer (IARC), the National Toxicology Program (NTP) or the American Conference of Governmental Industrial Hygienists (ACGIH). 12. ECOLOGICAL INFORMATION ECOTOXICOLOGICAL EFFECTS : The following results are for the product, unless otherwise indicated. ACUTE FISH RESULTS : Species Exposure LC50 Test Descriptor Bluegill Sunfish 96 hrs > 5,000 mg/l Similar Product Rainbow Trout 96 hrs > 8,000 mg/l Product SAFETY DATA SHEET PRODUCT 3D TRASAR 3DT120 EMERGENCY TELEPHONE NUMBER(S) (800) 424-9300 (24 Hours) CHEMTREC Nalco Company 1601 W. Diehl Road Naperville, Illinois 60563-1198 (630)305-1000 For additional copies of an MSDS visit and request access. 6 / 10 Inland Silverside 96 hrs 3,736 mg/l Similar Product ACUTE INVERTEBRATE RESULTS : Species Exposure LC50 EC50 Test Descriptor Daphnia magna 48 hrs 1,339 mg/l Product Mysid Shrimp (Mysidopsis bahia) 96 hrs 3,750 mg/l Similar Product PERSISTENCY AND DEGRADATION : Total Organic Carbon (TOC) : 120,000 mg/l Chemical Oxygen Demand (COD) : 300,000 mg/l Biological Oxygen Demand (BOD) : Incubation Period Value Test Descriptor 5 d 175 mg/l Product The organic portion of this preparation is expected to be poorly biodegradable. MOBILITY : The environmental fate was estimated using a level III fugacity model embedded in the EPI (estimation program interface) Suite TM, provided by the US EPA. The model assumes a steady state condition between the total input and output. The level III model does not require equilibrium between the defined media. The information provided is intended to give the user a general estimate of the environmental fate of this product under the defined conditions of the models. If released into the environment this material is expected to distribute to the air, water and soil/sediment in the approximate respective percentages; Air Water Soil/Sediment <5% 10 - 30% 70 - 90% The portion in water is expected to be soluble or dispersible. BIOACCUMULATION POTENTIAL This preparation or material is not expected to bioaccumulate. ENVIRONMENTAL HAZARD AND EXPOSURE CHARACTERIZATION Based on our hazard characterization, the potential environmental hazard is: Based on our recommended product application and the product's characteristics, the potential environmental exposure is: Low If released into the environment, see CERCLA/SUPERFUND in Section 15. 13. DISPOSAL CONSIDERATIONS If this product becomes a waste, it is not a hazardous waste as defined by the Resource Conservation and Recovery Act (RCRA) 40 CFR 261, since it does not have the characteristics of Subpart C, nor is it listed under Subpart D. SAFETY DATA SHEET PRODUCT 3D TRASAR 3DT120 EMERGENCY TELEPHONE NUMBER(S) (800) 424-9300 (24 Hours) CHEMTREC Nalco Company 1601 W. Diehl Road Naperville, Illinois 60563-1198 (630)305-1000 For additional copies of an MSDS visit and request access. 7 / 10 As a non-hazardous waste, it is not subject to federal regulation. Consult state or local regulation for any additional handling, treatment or disposal requirements. For disposal, contact a properly licensed waste treatment, storage, disposal or recycling facility. 14. TRANSPORT INFORMATION The information in this section is for reference only and should not take the place of a shipping paper (bill of lading) specific to an order. Please note that the proper Shipping Name / Hazard Class may vary by packaging, properties, and mode of transportation. Typical Proper Shipping Names for this product are as follows. LAND TRANSPORT : Proper Shipping Name : PRODUCT IS NOT REGULATED DURING TRANSPORTATION AIR TRANSPORT (ICAO/IATA) : Proper Shipping Name : PRODUCT IS NOT REGULATED DURING TRANSPORTATION MARINE TRANSPORT (IMDG/IMO) : Proper Shipping Name : PRODUCT IS NOT REGULATED DURING TRANSPORTATION 15. REGULATORY INFORMATION This section contains additional information that may have relevance to regulatory compliance. The information in this section is for reference only. It is not exhaustive, and should not be relied upon to take the place of an individualized compliance or hazard assessment. Nalco accepts no liability for the use of this information. NATIONAL REGULATIONS, USA : OSHA HAZARD COMMUNICATION RULE, 29 CFR : Our hazard evaluation has found that this product is not hazardous under 29 CFR CERCLA/SUPERFUND, 40 CFR 302 : Notification of spills of this product is not required. SARA/SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (TITLE III) - SECTIONS 302, 311, 312, AND 313 : SECTION 302 - EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355) : This product does not contain substances listed in Appendix A and B as an Extremely Hazardous Substance. SECTIONS 311 AND 312 - MATERIAL SAFETY DATA SHEET REQUIREMENTS (40 CFR 370) : Our hazard evaluation has found that this product is not hazardous under 29 CFR SAFETY DATA SHEET PRODUCT 3D TRASAR 3DT120 EMERGENCY TELEPHONE NUMBER(S) (800) 424-9300 (24 Hours) CHEMTREC Nalco Company 1601 W. Diehl Road Naperville, Illinois 60563-1198 (630)305-1000 For additional copies of an MSDS visit and request access. 8 / 10 Under SARA 311 and 312, the EPA has established threshold quantities for the reporting of hazardous chemicals. The current thresholds are: 500 pounds or the threshold planning quantity (TPQ), whichever is lower, for extremely hazardous substances and 10,000 pounds for all other hazardous chemicals. SECTION 313 - LIST OF TOXIC CHEMICALS (40 CFR 372) : This product does not contain substances on the List of Toxic Chemicals. TOXIC SUBSTANCES CONTROL ACT (TSCA) : The substances in this preparation are included on or exempted from the TSCA 8(b) Inventory (40 CFR 710) NSF NON-FOOD COMPOUNDS REGISTRATION PROGRAM (former USDA List of Proprietary Substances & Non-Food Compounds) : NSF Registration number for this product is : 141583 This product is acceptable for treatment of cooling and retort water (G5) in and around food processing areas. This product has been certified as KOSHER/PAREVE for year-round use INCLUDING THE PASSOVER SEASON by the CHICAGO RABBINICAL COUNCIL. FEDERAL WATER POLLUTION CONTROL ACT, CLEAN WATER ACT, 40 CFR / formerly Sec. 307, 40 CFR / formerly Sec. 311 : This product may contain trace levels (< for carcinogens, <1% all other substances) of the following substance(s) listed under the regulation. Additional components may be unintentionally present at trace levels. Substance(s) Citations Sodium Bisulfite Sulfuric Acid Sec. 311 CLEAN AIR ACT, Sec. 112 (Hazardous Air Pollutants, as amended by 40 CFR 63), Sec. 602 (40 CFR 82, Class I and II Ozone Depleting Substances) : Substances listed under this regulation are not intentionally added or expected to be present in this product. Listed components may be present at trace levels. CALIFORNIA PROPOSITION 65 : Substances listed under California Proposition 65 are not intentionally added or expected to be present in this product. MICHIGAN CRITICAL MATERIALS : Substances listed under this regulation are not intentionally added or expected to be present in this product. Listed components may be present at trace levels. STATE RIGHT TO KNOW LAWS : Substances listed under this regulation are not intentionally added or expected to be present in this product. Listed components may be present at trace levels. SAFETY DATA SHEET PRODUCT 3D TRASAR 3DT120 EMERGENCY TELEPHONE NUMBER(S) (800) 424-9300 (24 Hours) CHEMTREC Nalco Company 1601 W. Diehl Road Naperville, Illinois 60563-1198 (630)305-1000 For additional copies of an MSDS visit and request access. 9 / 10 INTERNATIONAL CHEMICAL CONTROL LAWS : CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA) : The substance(s) in this preparation are included in or exempted from the Domestic Substance List (DSL). AUSTRALIA All substances in this product comply with the National Industrial Chemicals Notification & Assessment Scheme (NICNAS). CHINA All substances in this product comply with the Provisions on the Environmental Administration of New Chemical Substances and are listed on the Inventory of Existing Chemical Substances China (IECSC). EUROPE The substances in this preparation have been reviewed for compliance with the EINECS or ELINCS inventories. JAPAN All substances in this product comply with the Law Regulating the Manufacture and Importation Of Chemical Substances and are listed on the Existing and New Chemical Substances list (ENCS). KOREA All substances in this product comply with the Toxic Chemical Control Law (TCCL) and are listed on the Existing Chemicals List (ECL) NEW ZEALAND All substances in this product comply with the Hazardous Substances and New Organisms (HSNO) Act 1996,and are listed on or are exempt from the New Zealand Inventory of Chemicals. PHILIPPINES All substances in this product comply with the Republic Act 6969 (RA 6969) and are listed on the Philippines Inventory of Chemicals & Chemical Substances (PICCS). 16. OTHER INFORMATION Due to our commitment to Product Stewardship, we have evaluated the human and environmental hazards and exposures of this product. Based on our recommended use of this product, we have characterized the product's general risk. This information should provide assistance for your own risk management practices. We have evaluated our product's risk as follows: * The human risk is: Low * The environmental risk is: Low Any use inconsistent with our recommendations may affect the risk characterization. Our sales representative will assist you to determine if your product application is consistent with our recommendations. Together we can implement an appropriate risk management process. SAFETY DATA SHEET PRODUCT 3D TRASAR 3DT120 EMERGENCY TELEPHONE NUMBER(S) (800) 424-9300 (24 Hours) CHEMTREC Nalco Company 1601 W. Diehl Road Naperville, Illinois 60563-1198 (630)305-1000 For additional copies of an MSDS visit and request access. 10 / 10 This product material safety data sheet provides health and safety information. The product is to be used in applications consistent with our product literature. Individuals handling this product should be informed of the recommended safety precautions and should have access to this information. For any other uses, exposures should be evaluated so that appropriate handling practices and training programs can be established to insure safe workplace operations. Please consult your local sales representative for any further information. REFERENCES Threshold Limit Values for Chemical Substances and Physical Agents and Biological Exposure Indices, American Conference of Governmental Industrial Hygienists, OH., (Ariel Insight CD-ROM Version), Ariel Research Corp., Bethesda, MD. Hazardous Substances Data Bank, National Library of Medicine, Bethesda, Maryland (TOMES CPS CD-ROM Version), Micromedex, Inc., Englewood, CO. IARC Monographs on the Evaluation of the Carcinogenic Risk of Chemicals to Man, Geneva: World Health Organization, International Agency for Research on Cancer. Integrated Risk Information System, Environmental Protection Agency, Washington, (TOMES CPS CD-ROM Version), Micromedex, Inc., Englewood, CO. Annual Report on Carcinogens, National Toxicology Program, Department of Health and Human Services, Public Health Service. Title 29 Code of Federal Regulations, Part 1910, Subpart Z, Toxic and Hazardous Substances, Occupational Safety and Health Administration (OSHA), (Ariel Insight CD-ROM Version), Ariel Research Corp., Bethesda, MD. Registry of Toxic Effects of Chemical Substances, National Institute for Occupational Safety and Health, Cincinnati, OH, (TOMES CPS CD-ROM Version), Micromedex, Inc., Englewood, CO. Ariel Insight (An integrated guide to industrial chemicals covered under major regulatory and advisory programs), North American Module, Western European Module, Chemical Inventories Module and the Generics Module (Ariel Insight CD-ROM Version), Ariel Research Corp., Bethesda, MD. The Teratogen Information System, University of Washington, Seattle, WA (TOMES CPS CD-ROM Version), Micromedex, Inc., Englewood, CO. Prepared By : SHE Department Date issued : 03/28/2011 Version Number :

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